Search results for "crosscoupling reactions"

showing 2 items of 2 documents

Naphthalene-2,6-diyl bis(4-methylbenzenesulfonate)

2018

The complete molecule of the title compound, C24H20O6S2, is generated by a crystallographic inversion centre at the middle of the naphthalene ring system. The dihedral angle between the naphthalene ring system and the pendant benzene ring is 10.23 (6)° and the C—S—O—C torsion angle is −172.05 (10)°. In the crystal, weak C—H...O interactions link the molecules into (10-1) sheets.

crystal structure010405 organic chemistryChemistryGeneral MedicineCrystal structureDihedral angle010402 general chemistryRing (chemistry)01 natural sciencesCoupling reactioncrosscoupling reactions0104 chemical sciencesCrystalCrystallographychemistry.chemical_compoundSulfonatecross-coupling reactionslcsh:QD901-999lcsh:CrystallographyPhysics::Chemical PhysicsBenzenetosylatesNaphthaleneIUCrData
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4-Chloronaphthalen-1-yl 4-methylbenzenesulfonate

2018

In the title compound, C17H13ClO3S, the naphthalene ring system and the benzene ring of the tosylate substituent are inclined to one another by 55.32 (5)°. The crystal structure features weak intermolecular C—H...O hydrogen bonds, one of which forms inversion dimers. Additional C—H...O hydrogen bonds and weak Cl...Cl halogen bonds stack the molecules along the b-axis direction.

crystal structure010405 organic chemistryChemistryHydrogen bondSubstituentGeneral MedicineCrystal structure010402 general chemistryRing (chemistry)01 natural sciencesMedicinal chemistryCoupling reactioncrosscoupling reactions0104 chemical scienceschemistry.chemical_compoundSulfonatecross-coupling reactionsHalogenlcsh:QD901-999lcsh:CrystallographyPhysics::Chemical PhysicsBenzenetosylatesIUCrData
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